Nanoparticle catalysed oxidation of sulfides to sulfones by in situ generated H2O2 in supercritical carbon dioxide/water biphasic medium

被引：49
|
作者：
Karmee, Sanjib Kumar [1 ]
Greiner, Lasse [1 ,2 ]
Kraynov, Alexander [3 ]
Mueller, Thomas E. [3 ]
Niemeijer, Bernd [1 ]
Leitner, Walter [1 ,4 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany
[2] DECHEMA EV, Karl Winnacker Inst, D-60486 Frankfurt, Germany
[3] Rhein Westfal TH Aachen, ITMC, CAT Catalyt Ctr, D-52074 Aachen, Germany
[4] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 36期
关键词：
HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; MILD OXIDATION; SULFUR-COMPOUNDS; SULFOXIDES; BENZENE; SILICA; OXYGEN; ADSORPTION; DESULFURIZATION;
D O I：
10.1039/c0cc01443e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In a one-pot reaction, hydrogen peroxide generated from H-2 and O-2 on a Pd catalyst was utilised as oxidant for the TiO2 catalyzed conversion of a sulfide to a sulfone. This transformation, where two different nanoparticle catalysts were employed in a supercritical carbon dioxide/water biphasic system, demonstrates the potential of compartmentalising catalytic processes in consecutive reactions.
引用
收藏
页码：6705 / 6707
页数：3
相关论文
共 50 条
  • [1] Practical oxidation of sulfides to sulfones by H2O2 catalysed by titanium catalyst
    Al-Maksoud, Walid
    Daniele, Stephane
    Sorokin, Alexander B.
    GREEN CHEMISTRY, 2008, 10 (04) : 447 - 451
  • [2] Highly Selective Oxidation of Sulfides to Sulfones by H2O2 Catalyzed by Porous Capsules
    Haddadi, Hedayat
    Korani, Elahe Mokhtari
    Hafshejani, Shahrbanou Moradpour
    Farsani, Mostafa Riahi
    JOURNAL OF CLUSTER SCIENCE, 2015, 26 (06) : 1913 - 1922
  • [3] Highly Selective Oxidation of Sulfides to Sulfones by H2O2 Catalyzed by Porous Capsules
    Hedayat Haddadi
    Elahe Mokhtari Korani
    Shahrbanou Moradpour Hafshejani
    Mostafa Riahi Farsani
    Journal of Cluster Science, 2015, 26 : 1913 - 1922
  • [4] Vanadium-catalyzed Selective Oxidation of Sulfides to Sulfoxides and Sulfones with H2O2
    Zhou, W. -Y.
    Chen, M.
    Zhang, P. -Z.
    Jia, A. -Q.
    Zhang, Q. -F.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 57 (05) : 816 - 824
  • [5] Vanadium-catalyzed Selective Oxidation of Sulfides to Sulfoxides and Sulfones with H2O2
    W.-Y. Zhou
    M. Chen
    P.-Z. Zhang
    A.-Q. Jia
    Q.-F. Zhang
    Russian Journal of Organic Chemistry, 2021, 57 : 816 - 824
  • [6] Propylene epoxidation with in situ generated H2O2 in supercritical conditions
    Prieto, Alejandro
    Palomino, Miguel
    Diaz, Urbano
    Corma, Avelino
    CATALYSIS TODAY, 2014, 227 : 87 - 95
  • [7] Selective oxidation of sulfides to sulfoxides catalysed by deep eutectic solvent with H2O2
    Dai, Dong-Yan
    Wang, Liang
    Chen, Qun
    He, Ming-Yang
    JOURNAL OF CHEMICAL RESEARCH, 2014, (03) : 183 - 185
  • [8] PARTIAL OXIDATION OF ETHANE BY IN-SITU GENERATED H2O2
    FRUSTERI, F
    SAVINOV, EN
    PARMALIANA, A
    SAVINOVA, ER
    PARMON, VN
    GIORDANO, N
    CATALYSIS LETTERS, 1994, 27 (3-4) : 355 - 360
  • [9] The first zinc-catalyzed oxidation of sulfides to sulfones using H2O2 as green oxidant
    Feng, Jian-Bo
    Gong, Jin-Long
    Wu, Xiao-Feng
    RSC ADVANCES, 2014, 4 (55) : 29273 - 29275
  • [10] Solvent free oxidation of sulfides to sulfones by H2O2 in the presence of chromium substituted polyoxometalate as catalyst
    Afrasiabi, Roozbeh
    Jalilian, Fariba
    Yadollahi, Bahram
    Farsani, Mostafa Riahi
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 50 : 113 - 116
12345