A novel solid oxide electrolysis cell (SOEC) to separate anodic from cathodic polarization under high electrolysis current

被引：30
|
作者：
Kim, Sun Jae [1 ]
Kim, Kun Joong [1 ]
Choi, Gyeong Man [1 ]
机构：
[1] Pohang Univ Sci & Technol POSTECH, Fuel Cell Res Ctr, Dept Mat Sci & Engn, Pohang 790784, South Korea
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 30期
基金：
新加坡国家研究基金会;
关键词：
Solid oxide electrolysis cell (SOEC); Yttria-stabilized zirconia; Separation of polarization resistance; Degradation; Air electrode; HIGH-TEMPERATURE ELECTROLYSIS; FUEL-CELLS; STABILIZED ZIRCONIA; HYDROGEN-PRODUCTION; PERFORMANCE; DELAMINATION; DEGRADATION;
D O I：
10.1016/j.ijhydene.2015.05.143
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel thick-film electrolyte-supported cell is constructed to separate cathodic (fuel electrode) from anodic (air electrode) polarization resistance R-p under high electrolysis current in a solid oxide electrolysis cell (SOEC). R-p of the SOEC are measured in various fuel humilities (40, 60, 80% H2O + balance H-2) at temperature of 650-800 degrees C and also compared those of a solid oxide fuel cell (SOFC). Anodic R-p of La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) is similar to 3 times larger than cathodic Rp of Ni-YSZ (yttria-stabilized zirconia) composite at all temperatures tested, so anodic polarization is the limiting factor of electrolysis performance. Degradation of polarization resistance also occurs mostly at the anode under electrolysis current (-800 mA/cm(2)). Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：9032 / 9038
页数：7
相关论文
共 50 条
  • [1] Polarization behavior of high temperature solid oxide electrolysis cells (SOEC)
    Momma, A
    Kato, T
    Kaga, Y
    Nagata, S
    [J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1997, 105 (05) : 369 - 373
  • [2] Origin of Polarization Losses in Solid Oxide Electrolysis Cells Under High Current Density
    Knibbe, R.
    Ebbesen, S. D.
    Mogensen, M.
    [J]. ELECTROCHEMICAL TECHNOLOGIES FOR HYDROGEN PRODUCTION, 2010, 28 (26): : 77 - 87
  • [3] Design and characterization of novel glass-ceramic sealants for solid oxide electrolysis cell (SOEC) applications
    Javed, Hassan
    Sabato, Antonio Gianfranco
    Herbrig, Kai
    Ferrero, Domenico
    Walter, Christian
    Salvo, Milena
    Smeacetto, Federico
    [J]. INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2018, 15 (04) : 999 - 1010
  • [4] Enhanced biomass-to-liquid (BTL) conversion process through high temperature co-electrolysis in a solid oxide electrolysis cell (SOEC)
    Pozzo, Matteo
    Lanzini, Andrea
    Santarelli, Massimo
    [J]. FUEL, 2015, 145 : 39 - 49
  • [5] Modeling a novel combined solid oxide electrolysis cell (SOEC) - Biomass gasification renewable methanol production system
    Ali, Shahid
    Sorensen, Kim
    Nielsen, Mads P.
    [J]. RENEWABLE ENERGY, 2020, 154 : 1025 - 1034
  • [6] Suspension Plasma Spraying to Manufacture Electrodes for Solid Oxide Fuel Cell (SOFC) and Solid Oxide Electrolysis Cell (SOEC)
    Marchand, O.
    Saoutieff, E.
    Bertrand, P.
    Planche, M. P.
    Tingaud, O.
    Bertrand, G.
    [J]. SOLID OXIDE FUEL CELLS 11 (SOFC-XI), 2009, 25 (02): : 585 - 594
  • [7] Process analysis of a novel coal-to-methanol technology for gasification integrated solid oxide electrolysis cell (SOEC)
    An, Haiquan
    Liu, Zhen
    Mu, Shujun
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (26) : 9805 - 9811
  • [8] High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC)
    G. Schiller
    A. Ansar
    M. Lang
    O. Patz
    [J]. Journal of Applied Electrochemistry, 2009, 39 : 293 - 301
  • [9] The influence of sulfur impurities in industrial COx gases on solid oxide electrolysis cell (SOEC) degradation
    Riegraf, Matthias
    Develos-Bagarinao, Katherine
    Biswas, Indro
    Costa, Remi
    [J]. JOURNAL OF POWER SOURCES, 2023, 559
  • [10] Fabrication of alloy foam-supported solid oxide electrolysis cell (SOEC) for hydrogen production
    Visvanichkul, Ramin
    Puengjinda, Pramote
    Jiwanuruk, Tara
    Peng-Ont, Saranya
    Sirimungkalakul, Nichaporn
    Ngampuengpis, Watcharin
    Sornchamni, Thana
    Kim-Lohsoontorn, Pattaraporn
    [J]. 2019 THE 2ND INTERNATIONAL SYMPOSIUM ON HYDROGEN ENERGY AND ENERGY TECHNOLOGIES (HEET 2019), 2020, 155
12345