Interpenetration network (IPN) assisted transcription of polymeric hollow spheres: A general approach towards composite hollow spheres

被引：14
|
作者：
Zhang, Chengliang [1 ]
Ding, Shujiang [1 ]
Li, Jianjun [1 ]
Xu, Huifang [1 ]
Sun, Lili [1 ]
Wei, Wei [1 ]
Li, Cuiping [1 ]
Liu, Jiguang [1 ]
Qu, Xiaozhong [1 ]
Lu, Yunfeng [2 ]
Yang, Zhenzhong [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
[2] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
来源：
POLYMER | 2008年 / 49卷 / 13-14期
基金：
中国国家自然科学基金;
关键词：
interpenetration networks (IPN); hollow spheres; composite;
D O I：
10.1016/j.polymer.2008.04.060
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We have demonstrated a general and facile method to synthesize composite hollow spheres by IPN-assisted transcription of polymeric hollow spheres. Starting from a parent PS hollow sphere, IPN polymer composite hollow spheres have been synthesized by a swell polymerization within the shell. The shell thickness and the cavity size are tunable by altering the feeding amount of the monomers. A variety of functional groups are derived by a selective modification of one network of the IPN polymer composite hollow spheres. By specific interactions of desired materials with gels, composite hollow spheres are obtained. The composition of the shell can be controlled within polymer, carbon, inorganic, metal and metallic compounds, and their composites. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3098 / 3102
页数：5
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