Syntheses, Structures and Magnetic Analysis of Co(II), Ni(II) Coordination Polymers Based on Pyridine-2,4,6-tricarboxylic Acid

被引:5
|
作者
Yin Xiu-Ju [1 ]
Liao Bei-Ling [1 ]
Wu Han-Min [1 ]
Pang Yi-Lin [1 ]
Li Shi-Xiong [1 ,2 ]
机构
[1] Hechi Univ, Coll Chem & Biol Engn, Yizhou 546300, Guangxi, Peoples R China
[2] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
关键词
coordination polymer; pyridine-2,4,6-tricarboxylic acid; magnetic; MOLECULE; PHOTOLUMINESCENCE; COMPLEXES;
D O I
10.11862/CJIC.2017.116
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title coordination polymers of ([M-3(pyta)(2)(H2O)(8)]center dot 4H(2)O}(n)(M=Co(1), Ni(2)) based on H(3)pyta (H3pyta=pyridine-2,4,6-tricarboxylic acid) had been synthesized under hydrothermal synthesis conditions with same temperature, molar ratio and solvent, but different metal salts. X-ray diffraction analysis shows that these two polymers are hetero-isomorphic and belong to the monoclinic system, P2(1)/c space group. The magnetic investigation shows that polymers 1 and 2 exhibit a ferromagnetic coupling between M(II) ions. CCDC: 1524314, 1; 1000880, 2.
引用
收藏
页码:1043 / 1050
页数:8
相关论文
共 22 条
  • [1] Distorted MnIVMn3III cubane complexes as single-molecule magnets
    Aubin, SMJ
    Wemple, MW
    Adams, DM
    Tsai, HL
    Christou, G
    Hendrickson, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (33) : 7746 - 7754
  • [2] Bei-Ling LIAO, 2016, CHINESE J INORG CHEM, V32, P1255
  • [3] Bourhis LJ, 2015, ACTA CRYSTALLOGR A, V71, P59, DOI [10.1107/S205327331402220759, 10.1107/S2053273314022207]
  • [4] First 3D Pr(III)-Ni(II)-Na(I) polymer and a 3D Pr(III) open network based on pyridine-2,4,6-tricarboxylic acid
    Gao, HL
    Yi, L
    Ding, B
    Wang, HS
    Cheng, P
    Liao, DZ
    Yan, SP
    [J]. INORGANIC CHEMISTRY, 2006, 45 (02) : 481 - 483
  • [5] Two Linear Trinuclear Clusters Based on Schiff Base: Syntheses, Structures and Magnetic Properties
    Huang, Xue Ren
    Yang, Li
    Zhou, Yu-Jie
    Zhang, Shu-hua
    Zhang, Hai Yang
    Hai, Hong
    [J]. JOURNAL OF CLUSTER SCIENCE, 2015, 26 (06) : 2033 - 2042
  • [6] Hydrothermal Synthesis, Structures and Magnetic Studies of Transition Metal Sulfates Containing Hydrazine
    Jia, Li-Hui
    Li, Ru-Yin
    Duan, Zhi-Ming
    Jiang, Shang-Da
    Wang, Bing-Wu
    Wang, Zhe-Ming
    Gao, Song
    [J]. INORGANIC CHEMISTRY, 2011, 50 (01) : 144 - 154
  • [7] Synthesis, structure, photoluminescence and magnetic properties of new 3-D lanthanide-pyridine-2,4,6-tricarboxylate frameworks
    Li, Cui-Jin
    Peng, Meng-Xia
    Leng, Ji-Dong
    Yang, Ming-Mei
    Lin, Zhuojia
    Tong, Ming-Liang
    [J]. CRYSTENGCOMM, 2008, 10 (11): : 1645 - 1652
  • [8] Syntheses, Structures and Magnetic Studies of Three Double Hydrazine Bridging Transition Metal Compounds
    Li Huan
    Chen Yun-Zhou
    Wang Yan-Jun
    Chen Yun-Feng
    Wang Bing-Wu
    Jia Li-Hui
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2016, 32 (12) : 2198 - 2204
  • [9] Syntheses, Structures, Fluorescence and Anticancer Activity of Co(II) and Ag(I) Complexes with 4-(3H)-Quinazolinone
    Li Shi-Xiong
    Liao Bei-Ling
    Luo Pei
    Jiang Yi-Min
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (02) : 291 - 296
  • [10] Self assembly of three new copper coordination polymers based on N-[(3-pyridine)-sulfonyl]aspartate: Synthesis and structure
    Liao, B. L.
    Li, S. X.
    Guo, J. J.
    Jia, J. J.
    Jiang, Y. M.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2016, 42 (04) : 285 - 291