Biomarkers, carbon isotopic composition and source rock potentials of Awgu coals, middle Benue trough, Nigeria

被引:15
|
作者
Adedosu, Taofik A. [1 ]
Sonibare, Oluwadayo O. [2 ]
Tuo, Jincai [3 ]
Ekundayo, Olusegun [2 ]
机构
[1] Ladoke Akintola Univ Technol, Dept Chem, Ogbomosho, Nigeria
[2] Univ Ibadan, Dept Chem, Petr & Environm Geochem Res Grp, Ibadan, Nigeria
[3] Chinese Acad Sci, Inst Geol & Geophys, Key Lab Petr Resources Res, Lanzhou 730000, Gansu, Peoples R China
关键词
Hydrocarbon generation; Source rock; Biomarkers; Coal; Thermal maturity; PALEOENVIRONMENTAL RECONSTRUCTION; GEOCHEMICAL INDICATORS; ORGANIC GEOCHEMISTRY; TERTIARY OILS; PARIS BASIN; CRUDE OILS; SEDIMENTS; MATURITY; ALKANES; SHALES;
D O I
10.1016/j.jafrearsci.2012.03.006
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Coal and carbonaceous shale samples were collected from two boreholes (BH 94 and BH 120) in Awgu formation of Middle Benue Trough, Nigeria. Source rock potentials of the samples were studied using biomarkers and carbon isotopic composition. Biomarkers in the aliphatic fractions in the samples were studied using Gas Chromatography-Mass Spectrometry (GC-MS). The Carbon isotope analysis of individual n-alkanes in the aliphatic fraction was performed using Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometer (GC-IRMS). The abundance of hopanes, homohopanes (C-31-C-35), and C-29 steranes in the samples indicate terrestrial plant, phytoplankton and cyanobacteria contributions to the organic matter that formed the coal. High (Pr/Ph) ratio (3.04-11.07) and isotopic distribution of individual alkanes showed that the samples consisted of mixed terrestrial/marine organic matter deposited under oxic condition in lacustrine-fluvial/deltaic depositional environment. The maturity parameters derived from biomarker distributions showed that the samples are in the main phase of oil window. (c) 2012 Elsevier Ltd. All rights reserved.
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页码:13 / 21
页数:9
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