Ruthenium-Indenylidene Olefin Metathesis Catalyst with Enhanced Thermal Stability

被引：33
|
作者：
Kabro, Anzhelika [1 ]
Roisnel, Thierry [2 ]
Fischmeister, Cedric [1 ]
Bruneau, Christian [1 ]
机构：
[1] Univ Rennes 1, CNRS, UMR Catalyse & Organometall 6226, Campus Beaulieu,263 Ave Gen Leclerc, F-35042 Rennes, France
[2] Univ Rennes 1, CNRS, UMR 6226, Ctr Diffractometrie 10, F-5042 Rennes, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 40期
关键词：
indenylidene; latent catalysts; metathesis; olefins; ruthenium; RING-CLOSING METATHESIS; N-HETEROCYCLIC CARBENE; HIGHLY-ACTIVE CATALYSTS; CROSS-METATHESIS; ALKENE METATHESIS; ALLENYLIDENE COMPLEXES; FATTY ESTERS; IN-SITU; EFFICIENT; BEARING;
D O I：
10.1002/chem.201001659
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new ruthenium complexes bearing a bidentate (kappa O-2, C)-isopropoxy- indenylidene ligand and a PPh3 (9) or PCy3 (10, Cy = cyclohexyl) ligand have been synthesized and fully characterized by H-1 and C-13 NMR spectroscopy and X-ray crystallography. Complex 10 displays a very high thermal stability with a half life of six days at 110 degrees C in [D-8] toluene. Complex 10 was evaluated in various ring-closing metathesis reactions and ring-opening metathesis polymerization of dicyclopentadiene, in which it showed a latent behavior with low activity at room temperature and high activity upon thermal activation.
引用
收藏
页码：12255 / 12261
页数：7
相关论文
共 50 条
  • [1] Recent advances in ruthenium-indenylidene mediated olefin metathesis
    Clavier, Herve
    Boeda, Fabien
    Nolan, Steven P.
    [J]. CHIMICA OGGI-CHEMISTRY TODAY, 2008, 26 (04) : 54 - 56
  • [2] Integrating Activity with Accessibility in Olefin Metathesis: An Unprecedentedly Reactive Ruthenium-Indenylidene Catalyst
    Nascimento, Daniel L.
    Gawin, Anna
    Gawin, Rafal
    Gunka, Piotr A.
    Zachara, Janusz
    Skowerski, Krzysztof
    Fogg, Deryn E.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (27) : 10626 - 10631
  • [3] Integrating Activity with Accessibility in Olefin Metathesis: An Unprecedentedly Reactive Ruthenium-Indenylidene Catalyst
    Nascimento, Daniel L.
    Gawin, Anna
    Gawin, Rafal
    Guńka, Piotr A.
    Zachara, Janusz
    Skowerski, Krzysztof
    Fogg, Deryn E.
    [J]. Journal of the American Chemical Society, 2019, 141 (27): : 10626 - 10631
  • [4] Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts
    Urbina-Blanco, Cesar A.
    Manzini, Simone
    Gomes, Jessica Perez
    Doppiu, Angelino
    Nolan, Steven P.
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (17) : 5022 - 5024
  • [5] Ruthenium-indenylidene complexes: powerful tools for metathesis transformations
    Boeda, Fabien
    Clavier, Herve
    Nolan, Steven P.
    [J]. CHEMICAL COMMUNICATIONS, 2008, (24) : 2726 - 2740
  • [6] Ruthenium-Indenylidene Complexes: Scope in Cross-Metathesis Transformations
    Boeda, Fabien
    Bantreil, Xavier
    Clavier, Herve
    Nolan, Steven P.
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (18) : 2959 - 2966
  • [7] Ruthenium-indenylidene initiators for living ring opening metathesis polymerisation
    Leitgeb, Anita
    Burtscher, Daniel
    Bauer, Thomas
    Slugovc, Christian
    [J]. CHIMICA OGGI-CHEMISTRY TODAY, 2009, 27 (03) : 30 - 32
  • [8] The Influence of Phosphane Ligands on the Versatility of Ruthenium-Indenylidene Complexes in Metathesis
    Broggi, Julie
    Urbina-Blanco, Cesar A.
    Clavier, Herve
    Leitgeb, Anita
    Slugovc, Christian
    Slawin, Alexandra M. Z.
    Nolan, Steven P.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (30) : 9215 - 9225
  • [9] A latent and controllable ruthenium-indenylidene catalyst for emulsion ROMP in water
    Ozturk, Bengi Ozgun
    Sehitoglu, Solmaz Karabulut
    Meier, Michael A. R.
    [J]. EUROPEAN POLYMER JOURNAL, 2015, 62 : 116 - 123
  • [10] Ring-Rearrangement Metathesis (RRM) Mediated by Ruthenium-Indenylidene Complexes
    Clavier, Herve
    Broggi, Julie
    Nolan, Steven P.
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (05) : 937 - 943
12345