Application of Glycidol in Synthesis of Oligoetherols with Perhydro-1,3,5-Triazine Ring

被引：6
|
作者：
Cyzio, Karina [1 ]
Lubczak, Jacek [1 ]
机构：
[1] Rzeszow Univ Technol, Dept Organ Chem, PL-35959 Rzeszow, Poland
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 122卷 / 01期
关键词：
heteroatom containing polymer; synthesis; oligomers; structure; polyurethanes; ETHYLENE CARBONATE; ISOCYANURIC ACID; POLYETHEROLS;
D O I：
10.1002/app.34131
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new method of preparation of oligoetherols containing perhydro-1,3,5-triazine rings from isocyanuric acid and an excess of glycidol, alkylene carbonates, or oxiranes is presented. The course of reaction was studied at various molar ratios of glycidol to isocyanuric acid. The structure of the products was established, and some physical properties were measured. The oligoetherols were demonstrated to be useful substrates for polyurethane foams of enhanced thermal stability. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 417-426, 2011
引用
收藏
页码：417 / 426
页数：10
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