Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides

被引：7

作者：

Hui, Rui-Hua ^{[1
]}

Zhou, Peng ^{[1
]}

You, Zhong-Lu ^{[2
]}

机构：

[1] Anshan Normal Univ, Dept Chem, Anshan 114007, Peoples R China

[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 01期

关键词：

azide; crystal structure; Schiff base; synthesis; zinc complex; LIGHT;

D O I：

10.1080/15533174.2011.609503

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two end-on azide-bridged dinuclear Schiff base zinc(II) complexes, [Zn2Br2(mu(1,1)-N-3)L-2(1)]center dot H2O (1) and [Zn2I2(mu(1,1)-N-3)L-2(2)]center dot I (2) (L-1 = 4-bromo-2-[(2-isopropylaminoethylimino)methyl]phenol, L-2 = 2-ethoxy-6-[(2-ethylaminoethylimino)methyl]phenol), have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. One Zn atom in (1) is five-coordinated in a square pyramidal geometry, while the other Zn atom in (1) and the Zn atoms in (2) are in tetrahedral geometries.

引用

页码：135 / 139

页数：5

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