Synthesis and surface treatment of magnetite nanoparticles for tuning hydrophobicity and colloidal stability

被引:2
|
作者
Jadhav, Sushilkumar A. [1 ,2 ,3 ]
Bongiovanni, Roberta [1 ]
Marchisio, Daniele [1 ]
机构
[1] Politecn Torino, Dept Appl Sci & Technol, I-10129 Turin, Italy
[2] Univ Turin, Dept Chem, I-10125 Turin, Italy
[3] Univ Turin, Nanostruct Interfaces & Surfaces NIS Ctr, I-10125 Turin, Italy
关键词
FUNCTIONALIZATION; NANOCOMPOSITES;
D O I
10.1134/S1061933X16040074
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Post-synthetic surface modification of magnetite nanoparticles synthesized by a modified co-precipitation process was carried out with triethoxy-terminated perfluoropolyether (PFPE) oligomers. The chemisorption of PFPE oligomers on the surface of magnetites was confirmed by ATR-FTIR and TGA analyses. The efficiency of surface modification of the oligomer to prevent the aggregation of magnetite nanoparticles was studied with the dynamic light scattering technique by measuring the hydrodynamic diameter and polydispersity index of the surface treated nanoparticles, together with their zeta potential. Aggregation kinetics profiles were constructed for surface treated nanoparticles. The obtained data was compared with magnetite nanoparticles treated with critic acid, to assess the efficiency of the surface modification with the PFPE oligomers. The comparison showed that the bifunctional PFPE oligomer treated nanoparticles are characterized by improved colloidal stability and hydrophobicity.
引用
收藏
页码:566 / 572
页数:7
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