Hydroxycarbonylation of 1-hexene catalyzed by [Rh(COD)(amine)2](PF6) complexes immobilized on poly(4-vinylpyridine)

被引：5
|
作者：
Hung-Low, F
Uzcátegui, GC
Alvarez, J
Ortega, MC
Pardey, AJ [1 ]
Longo, C
机构：
[1] Cent Univ Venezuela, Fac Ciencias, Escuela Quim, Ctr Equilibrios Soluc, Caracas, Venezuela
[2] Cent Univ Venezuela, Fac Farm, Ctr Invest & Desarrollo Radiofarm, Caracas, Venezuela
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 84卷 / 01期
关键词：
hydroxycarbonylation; heptanoic acid; 1-hexene; rhodium;
D O I：
10.1007/s11144-005-0194-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rhodium(I) complexes, [Rb(COD)(amine)(2)](PF6) (COD = 1,5-cyclooctadiene, an-tine = 4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with water catalyzed both the hydroxycarbonylation of 1-hexene to propionic acid and the water-gas shift reaction (WGSR). The role of the coordinated amine on the catalytic activity was examined.
引用
收藏
页码：87 / 92
页数：6
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