An Unusual and Facile Synthetic Route to Alumoles

被引：13

作者：

Li, Jiancheng ^{[1
]}

Wu, Peng ^{[1
,3
]}

Jiang, Wenjun ^{[1
]}

Li, Bin ^{[1
]}

Wang, Binju ^{[1
]}

Zhu, Hongping ^{[1
]}

Roesky, Herbert W. ^{[2
]}

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China

[2] Univ Gcttingen, Inst Anorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 25期

基金：

中国国家自然科学基金;

关键词：

aggregation-induced emission; aluminum; heterocycles; alumoles; tris(pentafluorophenyl)borane; AGGREGATION-INDUCED EMISSION; DIMERIC DIALKYLALUMINUM; TRIORGANOTIN CATIONS; REACTIVITY; ALUMINUM; 1,1-CARBOBORATION; DERIVATIVES; ALUMINACYCLOPROPENE; STANNOLES; 1,1-ORGANOBORATION;

D O I：

10.1002/anie.202000899

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N-chelate ligand and R=organic group) with B(C6F5)(3) proceeds through an intermediate with Al...eta(2)-C equivalent to C side-on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum-containing heterocycles. The synthetic process is described, and the characterization of compounds and computational calculations were carried out. Furthermore, alumoles 2 and 4 exhibit an aggregation-induced emission (AIE) of the bright yellow fluorescence.

引用

页码：10027 / 10031

页数：5

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