Iodohydroxylation of alkenes promoted by molecular and hypervalent(III) iodine

被引：25
|
作者：
De Corso, AR [1 ]
Panunzi, B [1 ]
Tingoli, M [1 ]
机构：
[1] Univ Naples Federico II, Dipartimento Sci Alimenti, I-80055 Portici, NA, Italy
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 41期
关键词：
D O I：
10.1016/S0040-4039(01)01509-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Several iodohydrins are isolated in good yields starting from the corresponding alkenes and a mixture of molecular iodine and phenyliodine(III)bis(trifluoroacetate) (BTI), in CH3CN-H2O as solvent, at -15 degreesC. Hypoiodous acid is added to the terminal carbon-carbon double bond in a Markovnikov fashion. Moreover, the stereochemical features of the products show the anti-stereospecificity of the addition. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：7245 / 7247
页数：3
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