Poly[[(1,10-phenanthroline)(μ-L-tartrato)zinc] hexahydrate]

被引:4
|
作者
Dong, Gui-Ying [1 ]
He, Cui-Hong [1 ]
Liu, Tong-Fei [1 ]
Cui, Guang-Hua [1 ]
Deng, Xiao-Chen [2 ]
机构
[1] Hebei United Univ, Coll Chem Engn, Tangshan 063009, Peoples R China
[2] Hebei United Univ, Qianan Coll, Tangshan 063009, Peoples R China
关键词
COORDINATION POLYMERS;
D O I
10.1107/S1600536811024780
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compouand {[Zn(C4H4O6)(C12H8N2)]center dot 6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C4H4O6)(C12H8N2) repeat units; the asymmetric unit consists of one Zn2+ cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water molecules. The Zn atom is in a distorted octahedral ZnN2O4 coordination environment. The crystal structure is stabilized by O-H center dot center dot center dot O hydrogen bonds and pi-pi stacking of the phenanthroline units [centroid-centroid distances in the range 3.552 (2)-3.625 (2) angstrom] occurs between the chains. The title compound is isotypic with the Cu and Mn analogues.
引用
收藏
页码:M1005 / U1702
页数:12
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