Ruthenium Carbonyl Complexes Containing Alkyl-Substituted Indenyl Ligands: Syntheses and Structures

被引：0

作者：

Liu Ying-Chun ^{[1
]}

Ma Zhi-Hong ^{[2
]}

Shang Cheng-Xi ^{[3
]}

Han Zhan-Gang ^{[1
]}

Zheng Xue-Zhong ^{[1
]}

Lin Jin ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China

[2] Hebei Med Univ, Coll Basic Med, Shijiazhuang 050017, Peoples R China

[3] Chengde Nursing Vocat Coll, Chengde 067000, Hebei, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 04期

关键词：

indenyl; ruthenium carbonyl; X-ray diffraction; structure; CRYSTAL-STRUCTURE; TETRACARBONYL DIRUTHENIUM; METAL; ISOMERIZATION; DERIVATIVES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the alkyl-substituted indenyl ligands [C9H7R] (R=CH2CH2CH3 (1), CH(CH3)(2) (2), C5H9 (3), CH2C6H5 (4), CH2CH=CH2 (5)) with Ru-3(CO)(12) in refluxing xylene or heptane gave the responding dinuclear metal carbonyl complexes [(eta(5)-C9H6R)Ru(CO)(mu-CO)](2) (R=CH2CH2CH3 (6), CH(CH3)(2) (7), C5H9 (8), CH2C6H5 (9), CH2CH=CH2 (10)), respectively, as well as the bridged diruthenium complex [(eta(5)-C9H6)(H3CH2C)CHCH(CH2CH3)(eta(5)-C9H6] [Ru (CO) (mu-CO)](2) (11). These complexes have been characterized by elemental analysis, IR, and H-1 NMR spectroscopy. The molecular structures of 6, 9, 10 and 11 were determined by X-ray diffraction analysis. CCDC: 937499, 6; 972340, 9; 944111, 10; 970734, 11.

引用

页码：774 / 780

页数：7

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