Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor

被引：4

作者：

Korsunskii, B. L. ^{[1
,2
]}

Samoilenko, N. G. ^{[1
]}

Deyun, E. V. ^{[1
]}

Il'chenko, A. O. ^{[3
]}

机构：

[1] Russian Acad Sci, Inst New Chem Problems, Chernogolovka 142432, Moscow Oblast, Russia

[2] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia

[3] Tech Univ, Moscow Engn Phys Inst, Moscow 115409, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2008年 / 2卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

Exothermic Reaction; Thermal Explosion; Representative Point; Bifurcation Curve; Autocatalytic Reaction;

D O I：

10.1134/S1990793108030159

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless "degree of conversion-temperature" coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates.

引用

页码：426 / 430

页数：5

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