Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes

被引：56
|
作者：
Wang, Weifan [1 ]
Luo, Man [1 ]
Yao, Weiwei [2 ]
Ma, Mengtao [1 ]
Pullarkat, Sumod A. [3 ]
Xu, Li [1 ]
Leung, Pak-Hing [3 ]
机构：
[1] Nanjing Forestry Univ, Dept Chem & Mat Sci, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China
[2] Nanjing Univ Chinese Med, Coll Pharm, Nanjing 210023, Jiangsu, Peoples R China
[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Catalyst-free; Solvent-free; Aldehyde; Cyanosilylation; Knoevenagel condensation; METAL-ORGANIC FRAMEWORK; TRIMETHYLSILYL CYANIDE; EFFICIENT; COMPLEX; HYDROBORATION; ACTIVATION; KETONES;
D O I：
10.1021/acssuschemeng.8b05486
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple catalyst-free and solvent-free method for the cyanosilylation of a variety of aldehydes with trimethylsilyl cyanide as well as the Knoevenagel condensation reaction of various aldehydes with malononitrile was developed. The developed protocol demonstrated high efficiency in the two C-C bond formation scenarios.
引用
收藏
页码：1718 / 1722
页数：9
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