Modification of fullerene C60 by phosphorylated diazo compounds

被引：17
|
作者：
Romanova, IP [1 ]
Musina, EI [1 ]
Nafikova, AA [1 ]
Zverev, VV [1 ]
Yakhvarov, DG [1 ]
Sinyashin, OG [1 ]
机构：
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 08期
关键词：
60]fullerene; O; O-diethyl alpha-diazoethyl- and O; O-diethyl alpha-diazobenzylphosphonates; phosphorylated methanofullerenes; electrochemistry; quantum-chemical calculations;
D O I：
10.1023/A:1026096403043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New representatives of phosphorylated methanofullerenes were prepared by the reactions of [60]fullerene with O,O-diethyl alpha-diazoethyl- and O,O-diethyl alpha-diazobenzylphosphonates. Electrochemical reduction of the above-mentioned products proceeded stepwise and reversibly.
引用
收藏
页码：1750 / 1757
页数：8
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