Borane-substituted imidazol-2-ylidenes: syntheses in vacuo

被引：22
|
作者：
Taylor, Alasdair W. [1 ]
Lovelock, Kevin R. J. [1 ]
Jones, Robert G. [1 ]
Licence, Peter [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
IONIC LIQUIDS; MASS-SPECTROMETRY; PHOTOELECTRON-SPECTROSCOPY; CARBENE COMPLEXES; VAPORIZATION; PHASE; DISTILLATION; TEMPERATURES; IMIDAZOLIUM; DERIVATIVES;
D O I：
10.1039/c0dt01240h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The serendipitous discovery of an efficient reactive distillation is reported. Two borane-substituted imidazol-2-ylidenes have been prepared in high yield from precursor tetrafluoroborate derived room temperature ionic liquids by reactive distillation at T > 500 K and p < 1 x 10(-4) mbar.
引用
收藏
页码：1463 / 1470
页数：8
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