Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex

被引：24
|
作者：
Zhao, Yaguang [3 ]
Dong, Huilong [1 ,2 ]
Li, Youyong [1 ,2 ]
Fu, Xuefeng [3 ]
机构：
[1] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China
[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Jiangsu, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 29期
关键词：
VINYL-ACETATE; POLY(ACRYLIC ACID); NITROXIDE; HYDROGELS; WATER; METHACRYLATES; COPOLYMERS; UNIVERSAL; CATALYSTS; STYRENE;
D O I：
10.1039/c2cc00114d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.
引用
收藏
页码：3506 / 3508
页数：3
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