Increasing visible-light absorption for photocatalysis with black BiOCl

被引:392
|
作者
Ye, Liqun [1 ]
Deng, Kejian [2 ,3 ]
Xu, Feng [4 ]
Tian, Lihong [1 ]
Peng, Tianyou [1 ]
Zan, Ling [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China
[3] S Cent Univ Nationalities, Minist Educ, Wuhan 430074, Peoples R China
[4] Lanzhou Univ, Key Lab Magnetism & Magnet Mat, MOE, Lanzhou 730000, Peoples R China
关键词
TIO2; PHOTOCATALYST; OXYGEN VACANCY; DEGRADATION; SURFACE; ZNO; BR; CL; ENHANCEMENT; ENERGY;
D O I
10.1039/c1cp22876e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Black BiOCl with oxygen vacancies was prepared by UV light irradiation with Ar blowing. The as-prepared black BiOCl sample showed 20 times higher visible light photocatalytic activity than white BiOCl for RhB degradation. The trapping experiment showed that the superoxide radical (O-2(center dot-)) and holes (h(+)) were the main active species in aqueous solution under visible light irradiation.
引用
收藏
页码:82 / 85
页数:4
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