Charge transfer in fullerene -: porphyrin-derived dyads studied with light-induced electron spin resonance

被引:11
|
作者
Wrobel, Danuta
Graja, Andrzej
Manikowski, Henryk
Lewandowska, Kornelia
机构
[1] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland
[2] Poznan Univ Tech, Inst Phys, Fac Tech Phys, PL-60965 Poznan, Poland
关键词
zinc porphyrin-based dyes; fullerene; porphyrin-fullerene dyads; light-induced electron spin resonance;
D O I
10.1016/j.chemphys.2007.06.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dyads of fullerene-porphyrin type and adequate reference porphyrins were investigated with light-induced electron spin resonance (LESR) spectroscopy. Charge localization and photoinduced electron transfer in the dyads were studied in the dark and under light illumination. It was stated that the LESR signal increases stepwise with the incident light and decreases very slowly when the light is switched-off. Photogeneration of porphyrin cation-radicals was observed and analyzed. The principal parameters of the LESR lines of the ion-radicals are determined. It was stated that the main ESR parameters of the porphyrins are weakly dependent on number of involved porphyrin molecules; these parameters are not noticeably changed after the dyad formation. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:165 / 170
页数:6
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