The use of microcapillary techniques to study the corrosion resistance of AZ91 magnesium alloy at the microscale

被引:58
|
作者
Krawiec, H. [1 ]
Stanek, S. [1 ]
Vignal, V. [2 ]
Lelito, J. [1 ]
Suchy, J. S. [1 ]
机构
[1] AGH Univ Sci & Technol, Fac Foundry Engn, PL-30059 Krakow, Poland
[2] Univ Bourgogne, CNRS, UMR 5209, ICB Lab Interdisciplinaire Carnot Bourgogne, F-21078 Dijon, France
关键词
Magnesium; Polarization; AFM; Pitting corrosion; Eutectic; LOCALIZED CORROSION; ELECTROCHEMICAL-BEHAVIOR; MECHANICAL-PROPERTIES; PITTING CORROSION; PURE MAGNESIUM; DIE-CAST; MICROSTRUCTURE; MG; PHASE; ADDITIONS;
D O I
10.1016/j.corsci.2011.05.054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The AZ91 alloy is composed of Mg-17(Al, Zn)(12) precipitates, an eutectic phase around these precipitates, AlMn intermetallic particles and an alpha-Mg solid solution (matrix). The corrosion behaviour of AZ91 was investigated at the microscale by means of the electrochemical microcell technique, which uses extremely small capillaries (diameters between 5 and 10 mu m). Experiments were conducted in 0.1 M NaClO4 at 25 degrees C. The beta-Mg-17(Al, Zn)(12) precipitates were found to have the highest corrosion resistance, whereas the eutectic phase was very active (pitting potential of approximately -1400 mV vs. Ag/AgCl). The alpha-Mg solid solution displayed better corrosion resistance than the eutectic phase. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3108 / 3113
页数:6
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