Total synthesis of the porphyrin mineral abelsonite and related petroporphyrins with five-membered exocyclic rings

被引：20
|
作者：
Zhang, B [1 ]
Lash, TD [1 ]
机构：
[1] Illinois State Univ, Dept Chem, Normal, IL 61790 USA
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 39期
关键词：
D O I：
10.1016/j.tetlet.2003.08.007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A reliable synthesis of porphyrins with five-membered exocyclic rings from b-bilenes has been developed. This methodology has been applied to the first total synthesis of the porphyrin mineral abelsonite, as well as the widespread petroporphyrin deoxophylloerythroetioporphyrin (DPEP) and its 3-desethyl analogue. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7253 / 7256
页数：4
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