Synthesis and atropisomerism of 2,2′-ortho disubstituted biphenyls

被引：6

作者：

Wang, C. H. ^{[1
]}

Reilly, J. ^{[1
]}

Brand, N. ^{[1
]}

Schwartz, S. ^{[1
]}

Alluri, S. ^{[1
]}

Chan, T. M. ^{[2
]}

Buevich, A. V. ^{[2
]}

Ganguly, A. K. ^{[1
]}

机构：

[1] Stevens Inst Technol, Dept Chem Chem Biol & Biomed Engn, Hoboken, NJ 07030 USA

[2] Merck Res Labs, Kenilworth, NJ 07033 USA

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 48期

关键词：

Radical cyclization; Atropisomerism; CONVERSION; ALCOHOLS;

D O I：

10.1016/j.tetlet.2010.09.010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The role of substitution on the aromatic rings for the synthesis of 2:2 disubstituted biphenyls has been investigated. Atropisomerism involved in the above ring system has been studied using NMR spectroscopy. The outcome of inter and intramolecular Heck reaction is discussed. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：6213 / 6215

页数：3

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