A new family of fullerene derivatives: fullerene-curcumin conjugates for biological and photovoltaic applications

被引：21

作者：

Castro, Edison ^{[1
]}

Ceron, Maira R. ^{[1
,2
]}

Garcia, Andrea Hernandez ^{[1
]}

Kim, Quentin ^{[1
]}

Etcheverry-Berrios, Alvaro ^{[3
]}

Morel, Mauricio J. ^{[3
]}

Diaz-Torres, Raul ^{[4
]}

Qian, Wenjie ^{[4
]}

Martinez, Zachary ^{[5
]}

Mendez, Lois ^{[1
]}

Perez, Frank ^{[1
]}

Santoyo, Christy A. ^{[1
]}

Gimeno-Munoz, Raquel ^{[4
]}

Esper, Ronda ^{[1
]}

Gutierrez, Denisse A. ^{[5
]}

Varela-Ramirez, Armando ^{[5
]}

Aguilera, Renato J. ^{[5
]}

Llano, Manuel ^{[5
]}

Soler, Monica ^{[3
]}

Aliaga-Alcalde, Nuria ^{[4
,6
]}

Echegoyen, Luis ^{[1
]}

机构：

[1] Univ Texas El Paso, Dept Chem, 500W Univ Ave, El Paso, TX 79968 USA

[2] Lawrence Livermore Natl Lab, Phys & Life Sci, 7000 East Ave, Livermore, CA 94550 USA

[3] Univ Chile, Fac Ciencias Fis & Matemat, Dept Ingn Quim Biotechnol & Mat, Beauchef 851, Santiago, Chile

[4] Campus Univ Autonoma Barcelona, CSIC, ICMAB Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain

[5] Univ Texas El Paso, Border Biomed Res Ctr, Dept Biol Sci, 500 West Univ Ave, El Paso, TX 79968 USA

[6] ICREA, Passeig Lluis Co 23, Barcelona 08010, Spain

来源：

RSC ADVANCES | 2018年 / 8卷 / 73期

基金：

美国国家科学基金会;

关键词：

STABILITY; PROTEASE; CELLS; ANTIOXIDANTS; PERFORMANCE; INHIBITION; MATURATION; CHEMISTRY; C-60; DYE;

D O I：

10.1039/c8ra08334g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of a family of [60]fullerocurcuminoids obtained via Bingel reactions is reported. The new C-60 derivatives include curcumin and curcuminoids with a variety of end groups. Preliminary biological experiments show the potential activity of the compound containing a curcumin addend, which exhibits moderate anti-HIV-1 and radical scavenger properties, but no anti-cancer activity. In addition, the new fullerocurcuminoids exhibit HOMO/LUMO energy levels that are reasonably matched with those of perovskites and when they were tested in perovskite solar cells (PSCs) as the electron transporting material (ETM), photoconversion efficiencies ranging from 14.04-14.95% were obtained, whereas a value of 16.23% was obtained for [6,6]-phenyl-C-61-butyric acid methyl ester (PC61BM) based devices.

引用

页码：41692 / 41698

页数：7

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[1] A new family of fullerene derivatives: fullerene-curcumin conjugates for biological and photovoltaic applications (vol 8, pg 41692, 2018)
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Garcia, Andrea Hernandez
Kim, Quentin
Etcheverry-Berrios, Alvaro
Morel, Mauricio J.
Diaz-Torres, Raul
Qian, Wenjie
Martinez, Zachary
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Perez, Frank
Santoyo, Christy A.
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Esper, Ronda
Gutierrez, Denisse A.
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