One-dimensional coordination polymers generated from an oxadiazole-containing N,N′-bipyridine-type ligand and inorganic salts

被引：28
|
作者：
Dong, YB [1 ]
Cheng, JY
Ma, JP
Wang, HY
Huang, RQ
Guo, DS
Smith, MD
机构：
[1] Shandong Normal Univ, Coll Chem, Jinan 250014, Peoples R China
[2] Key Lab Chem Funct Mat, Jinan 250014, Peoples R China
来源：
SOLID STATE SCIENCES | 2003年 / 5卷 / 08期
关键词：
coordination polymers; (1,3,4)-oxadiazole-containing ligands; self-assembly;
D O I：
10.1016/S1293-2558(03)00124-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new one-dimensional coordination polymers have been prepared using Hg(II), Ag(I) and Zn(II) inorganic salts in combination with 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (L6). The compounds were characterized by single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In the solid state, compounds 1 and 3 (1: monoclinic, P2(1) /n, a = 5.5373 (3) Angstrom, b = 16.7839(9) Angstrom, c = 16.8120(9) Angstrom, beta = 92.8610(10)degrees, V = 1560.52(15) Angstrom(3), Z = 4; 3: monoclinic, P2(1) /n, a = 7.2958(4) Angstrom, b = 11.7214(6) Angstrom, c = 16.3979(9) Angstrom, beta = 101. 1150(10)degrees, V 1375.99(13) Angstrom(3), Z = 4) feature novel one-dimensional helical chain motif. Compound 2, however, (2: monoclinic, P2(1)/c, a = 5.5506(4) Angstrom, b = 16.5895(12) Angstrom, c = 16.6871(11) Angstrom, beta = 95.424(2)degrees, V = 1529.70(19) Angstrom(3), Z =4) exhibits one-dimensional zigzag chain motif, which result from the different conformations adopted by the L6 ligand and also the different metal coordination geometry. The luminescent properties of three new compounds were investigated in the solid state. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码：1177 / 1186
页数：10
相关论文
共 50 条
  • [1] One-dimensional coordination polymers generated from an oxadiazole-containing N,N′-bipyridine-type ligand and Cu(II) salts
    Dong, YB
    Ma, JP
    Smith, MD
    Huang, RQ
    Tang, B
    Guo, DS
    Wang, JS
    Loye, HCZ
    [J]. SOLID STATE SCIENCES, 2003, 5 (04) : 601 - 610
  • [2] Synthesis and characterization of new coordination polymers generated from oxadiazole-containing organic ligands and inorganic silver(I) salts
    Dong, YB
    Ma, JP
    Huang, RQ
    Smith, MD
    zur Loye, HC
    [J]. INORGANIC CHEMISTRY, 2003, 42 (02) : 294 - 300
  • [3] Synthesis and characterization of new coordination polymers generated from oxadiazole-containing ligand and inorganic M(II) [M = Cu(II), Co(II)] salts
    Dong, YB
    Ma, JP
    Huang, RQ
    Liang, FZ
    Smith, MD
    [J]. DALTON TRANSACTIONS, 2003, (08) : 1472 - 1479
  • [4] New coordination polymers and supramolecular complexes generated from oxadiazole-containing organic ligands and inorganic M(II) (M = Zn and Cu) salts
    Dong, YB
    Cheng, JY
    Wang, HY
    Huang, RQ
    Tang, B
    Smith, MD
    zur Loye, HC
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (13) : 2593 - 2604
  • [5] Coordination-directed one-dimensional coordination polymers generated from a new unsymmetrical oxadiazole bridging ligand and transition metal ions
    Song, Zhi-Gang
    Geng, Cui-Hong
    Ma, Jian-Ping
    Dong, Yu-Bin
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (07) : 809 - 813
  • [6] Two versatile N,N′-bipyridine-type ligands for preparing organic-inorganic coordination polymers:: New cobalt- and nickel-containing framework materials
    Ciurtin, DM
    Dong, YB
    Smith, MD
    Barclay, T
    zur Loye, HC
    [J]. INORGANIC CHEMISTRY, 2001, 40 (12) : 2825 - 2834
  • [7] Synthesis and characterization of new coordination polymers generated from oxadiazole-containing ligands and IIB metal ions
    Cheng, JY
    Dong, YB
    Huang, RQ
    Smith, MD
    [J]. INORGANICA CHIMICA ACTA, 2005, 358 (04) : 891 - 902
  • [8] Novel one-dimensional coordination polymers and a hydrogen-bonded supramolecular complex generated from a new unsymmetric oxadiazole bridging ligand and Cu(II) salts
    Wang, P
    Dong, YB
    Ma, JP
    Huang, RQ
    Smith, MD
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (07) : 596 - 599
  • [9] Syntheses and characterizations of one-dimensional coordination polymers generated from cadmium nitrate and bipyridine ligands
    Dong, YB
    Layland, RC
    Smith, MD
    Pschirer, NG
    Bunz, UHF
    zur Loye, HC
    [J]. INORGANIC CHEMISTRY, 1999, 38 (13) : 3056 - 3060
  • [10] New coordination polymers generated from oxadiazole-containing bidentate ligands and Cu-Cu dimetal units
    Dong, YB
    Ma, JP
    Smith, MD
    Huang, RQ
    Tang, B
    Chen, D
    zur Loye, HC
    [J]. SOLID STATE SCIENCES, 2002, 4 (10) : 1313 - 1320
12345