Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis

被引：65

作者：

Bianchini, C ^{[1
]}

Meli, A ^{[1
]}

Oberhauser, W ^{[1
]}

机构：

[1] CNR, ICCOM, I-50132 Florence, Italy

来源：

DALTON TRANSACTIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b303502f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article addresses fundamental. mechanistic aspects related to the perfectly alternating copolymerisation of CO and ethene in MeOH through the analysis of both actual reactions catalysed by palladium(II)-diphosphine precursors and stoichiometric reactions with model compounds. Most recent in situ studies of CO/ethene copolymerisation, applying high-pressure IR and NMR techniques, have been reviewed and commented.

引用

页码：2627 / 2635

页数：9

共 39 条

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Bianchini, C
Meli, A
Müller, G
Oberhauser, W
Passaglia, E
ORGANOMETALLICS, 2002, 21 (23) : 4965 - 4977
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Drent, E
van Dijk, R
van Ginkel, R
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Pugh, RI
CHEMICAL COMMUNICATIONS, 2002, (09) : 964 - 965
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Bianchini, C
Lee, HM
Meli, A
Oberhauser, W
Peruzzini, M
Vizza, F
ORGANOMETALLICS, 2002, 21 (01) : 16 - 33
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Jian Chao YUAN
ChineseChemicalLetters, 2001, (06) : 519 - 522
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Yuan, JC
Zhang, YH
Lu, SJ
CHINESE CHEMICAL LETTERS, 2001, 12 (06) : 519 - 522
[6] Palladium(II)-catalyzed alternating copolymerization of allene with carbon monoxide and the synthesis of terpolymer with alt-allene carbon monoxide and alt-ethene carbon monoxide blocks. Synthetic and mechanistic aspects
Kacker, S
Sen, A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (42) : 10028 - 10033
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BATISTINI, A
CONSIGLIO, G
ORGANOMETALLICS, 1992, 11 (05) : 1766 - 1769
[8] New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene
Bianchini, C
Lee, HM
Meli, A
Oberhauser, W
Vizza, F
Brüggeller, P
Rainer, HB
Langes, C
CHEMICAL COMMUNICATIONS, 2000, (09) : 777 - 778
[9] Regio- and stereoselective alternating copolymerization of α-olefins with carbon monoxide using a cationic palladium-chiral diphosphine catalyst
Yuan, JC
Lu, SJ
TETRAHEDRON LETTERS, 2001, 42 (24) : 4069 - 4073
[10] A Highly Efficient Chiral-Bridged Diphosphine Ligand Modified Cationic Palladium(II) Catalyst System for Asymmetric Alternating Copolymerization of Propene and Carbon Monoxide
Cui, Yuming
Wang, Lailai
Kwong, Fuk Yee
Tse, Man Kin
Chan, Albert S. C.
SYNLETT, 2009, (16) : 2696 - 2700

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