Chiral ionic liquids: A compendium of syntheses and applications (2005-2012)

被引:118
|
作者
Payagala, Tharanga [1 ]
Armstrong, Daniel W. [1 ]
机构
[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA
关键词
chiral ionic liquids; chiral discrimination; asymmetric synthesis; DIELS-ALDER REACTION; MICELLAR ELECTROKINETIC CHROMATOGRAPHY; ASYMMETRIC MICHAEL ADDITION; BAYLIS-HILLMAN REACTION; MODE ESI-MS; HIGHLY EFFICIENT ORGANOCATALYSTS; MASS-SPECTROMETRIC ANALYSIS; AMINO-ACID DERIVATIVES; STATIONARY PHASES; GAS-CHROMATOGRAPHY;
D O I
10.1002/chir.21975
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
In recent years, the field of chiral ionic liquids (CILs) has undergone exponential growth. As the technology has advanced, new ways of synthesizing stable and structurally diverse ionic liquids have been established. This has led to heretofore unknown applications of CILs as well as in improving efficiency of previously identified applications. In this review article we have compiled a comprehensive database containing structures and physical properties of notable CILs that have been synthesized during the last 6 years. Their applications in the fields of asymmetric organic synthesis, spectroscopy, and chromatography are also illustrated. This is an expansion of our previous review, which covered the literature before 2005. Chirality, 2011. (C) 2011 Wiley Periodicals, Inc.
引用
收藏
页码:17 / 53
页数:37
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