Synthesis and Thin Film Phase Behaviour of Functional Rod-Coil Block Copolymers Based on Poly(para-phenylenevinylene) and Poly(lactic acid)

被引：8
|
作者：
Braun, Christoph H. [1 ,2 ,3 ]
Schoepf, Benjamin [1 ,2 ,3 ]
Ngov, Chheng [4 ]
Brochon, Cyril [4 ,5 ]
Hadziioannou, Georges [4 ,5 ]
Crossland, Edward J. W. [1 ,2 ]
Ludwigs, Sabine [1 ,2 ,3 ]
机构：
[1] Univ Freiburg, Freiburger Mat Forschungszentrum, D-79104 Freiburg, Germany
[2] Univ Freiburg, Freiburg Inst Adv Studies, D-79104 Freiburg, Germany
[3] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany
[4] Univ Strasbourg, LIPHT ECPM, F-67087 Strasbourg, France
[5] Univ Bordeaux 1, Lab Chim Polymeres Organ, ENSCBP, Inst Polytech Bordeaux,CNRS UMR 5629, F-33607 Pessac, France
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2011年 / 32卷 / 11期
关键词：
atomic force microscopy; conjugated polymers; diblock copolymers; phase separation; thin films; ACCEPTOR DIBLOCK COPOLYMERS; EXCITON DIFFUSION; RADICAL POLYMERIZATION; PHOTOVOLTAIC APPLICATIONS; NANOWIRE ARRAYS; SOLAR-CELLS; DONOR; TEMPLATES; SURFACE; POLY(3-HEXYLTHIOPHENE);
D O I：
10.1002/marc.201100012
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the synthesis of a series of block copolymers consisting of a rod-like semiconducting poly(2,5-di(2'-ethylhexyloxy)-1,4-phenylenevinylene) (DEH-PPV) block and a flexible poly(lactic acid) (PLA) block that can be selectively degraded under mild conditions. Such selectively degradable block copolymers are designed as self-assembling templates for bulk heterojunction donor-acceptor layers in organic solar cells. A lamellar microphase-separated domain structure was identified for block copolymers with PLA volume fractions between 29 and 79% in bulk and thin films using SAXS, TEM, and AFM. Depending on the ratio of the two blocks we find either lamellae oriented parallel or perpendicular to the substrate in thin films.
引用
收藏
页码：813 / 819
页数：7
相关论文
共 50 条
  • [1] Thin film structure of symmetric rod-coil block copolymers
    Olsen, Bradley D.
    Li, Xuefa
    Wang, Jin
    Segalman, Rachel A.
    MACROMOLECULES, 2007, 40 (09) : 3287 - 3295
  • [2] Synthesis and Self-Assembly of Poly(diethylhexyloxy-p-phenylenevinylene)-b-poly(methyl methacrylate) Rod-Coil Block Copolymers
    Ho, Chun-Chih
    Lee, Yi-Huan
    Dai, Chi-An
    Segalman, Rachel A.
    Su, Wei-Fang
    MACROMOLECULES, 2009, 42 (12) : 4208 - 4219
  • [3] Synthesis and characterization of rod-coil poly(amide-block-aramid) alternating block copolymers
    de Ruijter, Christiaan
    Jager, Wolter F.
    Groenewold, Jan
    Picken, Stephen J.
    MACROMOLECULES, 2006, 39 (11) : 3824 - 3829
  • [4] Synthesis and characterization of a poly(para-phenyleneethynylene)-block-poly(ethylene oxide) rod-coil block copolymer
    Francke, V
    Rader, HJ
    Geerts, Y
    Mullen, K
    MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (06) : 275 - 281
  • [5] Synthesis of polypeptide based rod-coil block copolymers
    Steig, S
    Cornelius, F
    Witte, P
    Staal, BBP
    Koning, CE
    Heise, A
    Menzel, H
    CHEMICAL COMMUNICATIONS, 2005, (43) : 5420 - 5422
  • [6] Synthesis and characterization of novel rod-coil (tadpole) poly(linoleic acid) based graft copolymers
    Özge İnce
    Elvan Akyol
    Elvan Sulu
    Timur Şanal
    Baki Hazer
    Journal of Polymer Research, 2016, 23
  • [7] Synthesis and characterization of novel rod-coil (tadpole) poly(linoleic acid) based graft copolymers
    Ince, Ozge
    Akyol, Elvan
    Sulu, Elvan
    Sanal, Timur
    Hazer, Baki
    JOURNAL OF POLYMER RESEARCH, 2015, 23 (01) : 1 - 10
  • [8] Lyotropic rod-coil poly(amide-block-aramid) alternating block copolymers:: Phase behavior and structure
    de Ruijter, Christiaan
    Jager, Wolter F.
    Li, Liangbin
    Picken, Stephen J.
    MACROMOLECULES, 2006, 39 (13) : 4411 - 4417
  • [9] Synthesis of rod-coil block copolymers via end-functionalized poly(p-phenylene)s
    Marsitzky, D
    Brand, T
    Geerts, Y
    Klapper, M
    Mullen, K
    MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (07) : 385 - 389
  • [10] Vertically Oriented Nanostructures of Poly(3-dodecylthiophene)-Containing Rod-Coil Block Copolymers
    Lee, Kyu Seong
    Lee, Jaeyong
    Choi, Chungryong
    Seo, Yeseong
    Moon, Hong Chul
    Kim, Jin Kon
    MACROMOLECULES, 2018, 51 (13) : 4956 - 4965
12345