A Kinetics Study of the Non-catalytic Supercritical Transesterification Reaction for Biodiesel Production

被引:1
|
作者
Tan, K. T. [1 ]
Lee, K. T. [2 ]
Mohamed, A. R. [2 ]
机构
[1] Univ Tunku Abdul Rahman, Dept Petrochem Engn, Fac Engn & Green Technol, Kampar 31900, Perak, Malaysia
[2] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal, Pulau Pinang, Malaysia
关键词
activation energy; Arrhenius equation; biodiesel; kinetics; supercritical methanol; METHANOL; OIL; TECHNOLOGY;
D O I
10.1080/15567036.2011.592915
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In the present study, a kinetics study of non-catalytic supercritical transesterification reaction for biodiesel production was conducted. The kinetics model was developed by employing a three-step reversible reaction in supercritical transesterification reaction. Important kinetics parameters, such as pre-exponential factors and activation energy, were obtained and compared with other reported studies. In the results, the developed model was found to be adequate and significant. Furthermore, it could predict the yield of FAME and other intermediate compounds with marginal error.
引用
收藏
页码:705 / 713
页数:9
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