Imine-Linked Microporous Polymer Organic Frameworks

被引：205
|
作者：
Pandey, Prativa [1 ]
Katsoulidis, Alexandros P. [1 ]
Eryazici, Ibrahim [1 ]
Wu, Yuyang [1 ]
Kanatzidis, Mercouri G. [1 ]
Nguyen, SonBinh T. [1 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
CHEMISTRY OF MATERIALS | 2010年 / 22卷 / 17期
关键词：
HIGH-SURFACE-AREA; HYDROGEN STORAGE; NETWORKS; CRYSTALLINE; ADSORPTION; ROBUST; PIMS;
D O I：
10.1021/cm101157w
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Imine-linked microporous polymer organic frameworks (POFs) were synthesized via Schiff base condensation between 1,3,5-triformylbenzene and several readily available diamine monomers. Our facile, one-pot approach results in quantitative yields of POFs with the flexibility to incorporate several functional groups in their pores for tuning the interaction of their surface with different guest molecules. Synthesized POFs exhibit high specific surface areas (up to 1500 m(2) g(-1)) as well as high isosteric heats of H(2) adsorption (up to 8.2 kJ mol(-1)).
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页码：4974 / 4979
页数：6
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