Synthesis, spectroscopic and structural characterization of cobalt(II) complex with bis(3,5-dimethyl-1-pyrazolyl)methane and its application in catalytic alkanes oxidation with tert-butyl hydroperoxide

被引：0
|
作者：
Zhang, L [1 ]
Liu, QH
Peng, F
Du, M
机构：
[1] S China Univ Technol, Dept Chem Engn, Guangzhou 510640, Peoples R China
[2] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 30074, Peoples R China
来源：
POLISH JOURNAL OF CHEMISTRY | 2005年 / 79卷 / 04期
关键词：
catalytic oxidation; crystal structure; biomimetic hydroxylation; cobalt complex;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel cobalt complex, [Co(bdpm)(OBz)](ClO4) (bdpm = bis(3,5-dimethyl-1-pyrazolyl)methane, OBz = benzoate), was synthesized and characterized by elemental analysis, UV-Vis, IR spectroscopy and X-ray diffraction. The complex crystallizes in the trigonal system, space group P3(1)21 with a = 19.2583(9), b = 19.2583(9), c = 25.5269(17) angstrom and gamma = 120 degrees. The complex can catalyze the selective oxidation of alkanes to corresponding alcohols and ketones, and a presumptive mechanism was proposed.
引用
收藏
页码：655 / 661
页数：7
相关论文
共 50 条
  • [1] Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane
    Neves, Patricia
    Gago, Sandra
    Balula, Salete S.
    Lopes, Andre D.
    Valente, Anabela A.
    Cunha-Silva, Luis
    Almeida Paz, Filipe A.
    Pillinger, Martyn
    Rocha, Joao
    Silva, Carlos M.
    Goncalves, Isabel S.
    [J]. INORGANIC CHEMISTRY, 2011, 50 (08) : 3490 - 3500
  • [2] UNUSUAL ELECTRONIC-SPECTRA OF THE PSEUDOTETRAHEDRAL COMPLEX [TRIS((3,5-DIMETHYL-1-PYRAZOLYL)ETHYL)AMINE]COBALT(II) BIS(TETRAPHENYLBORATE)
    BANCI, L
    BENELLI, C
    GATTESCHI, D
    MANI, F
    [J]. INORGANIC CHEMISTRY, 1982, 21 (03) : 1133 - 1136
  • [3] THERMAL-ANALYSIS OF COBALT(II), NICKEL(II), COPPER(II) AND ZINC(II) BIS (3,5-DIMETHYL-1-PYRAZOLYL)DIHYDROBORATES
    CEIPIDOR, UB
    TOMASSETTI, M
    BONATI, F
    CURINI, R
    DASCENZO, G
    [J]. THERMOCHIMICA ACTA, 1983, 63 (01) : 59 - 66
  • [4] Synthesis, structural characterization, antibacterial activity and computational studies of new cobalt (II) complexes with 1,1,3,3-tetrakis (3,5-dimethyl-1-pyrazolyl)propane ligand
    Beheshti, Azizolla
    Safaeiyan, Forough
    Hashemi, Faeze
    Motamedi, Hossein
    Mayer, Peter
    Bruno, Giuseppe
    Rudbari, Hadi Amiri
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2016, 1123 : 225 - 237
  • [5] Structural characterization of five-coordinate copper(II), nickel(II), and cobalt(II) thiocyanato complexes derived from bis(2-(3,5-dimethyl-1-pyrazolyl)ethyl)amine
    Massoud, Salah S.
    Le Quan, Lucie
    Gatterer, Karl
    Albering, Jorg H.
    Fischer, Roland C.
    Mautner, Franz A.
    [J]. POLYHEDRON, 2012, 31 (01) : 601 - 606
  • [6] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF VOLATILE POLY(3,5-DIMETHYL-1-PYRAZOLYL)BORATE-COMPLEXES OF CA, SR, AND BA
    BELDERRAIN, TR
    CONTRERAS, L
    PANEQUE, M
    CARMONA, E
    MONGE, A
    RUIZ, C
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) : C5 - C7
  • [7] SYNTHESIS OF A NOVEL MU-OXO BINUCLEAR COPPER(II) COMPLEX LIGATED BY HYDROTRIS(3,5-DIMETHYL-1-PYRAZOLYL)BORATE
    KITAJIMA, N
    KODA, T
    MOROOKA, Y
    [J]. CHEMISTRY LETTERS, 1988, (02) : 347 - 350
  • [8] ORGANOPLATINUM(IV) COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF DIMETHYLPLATINUM(IV) COMPOUNDS WITH CHELATING NITROGEN DONOR LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF DIMETHYL[BIS(1-PYRAZOLYL)METHANE]PLATINUM DIIODIDE AND DIMETHYL[BIS(3,5-DIMETHYL-1-PYRAZOLYL)METHANE]PLATINUM DIIODIDE
    CLARK, HC
    FERGUSON, G
    JAIN, VK
    PARVEZ, M
    [J]. ORGANOMETALLICS, 1983, 2 (07) : 806 - 810
  • [9] Synthesis, structural characterization and spectroscopic properties of [Pt(bddn)]Cl2•3.5H2O (bddn=1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane)
    de Leon, Antonio
    Pons, Josefina
    Garcia-Anton, Jordi
    Solans, Xavier
    Font-Bardia, Merce
    Ros, Josep
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (12) : 801 - 805
  • [10] Synthesis, Structural Characterization and Spectroscopic Properties of [Pt(bddn)]Cl2 · 3.5H2O (bddn = 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonane)
    Antonio de Leon
    Josefina Pons
    Jordi García-Antón
    Xavier Solans
    Mercè Font-Bardia
    Josep Ros
    [J]. Journal of Chemical Crystallography, 2007, 37 : 801 - 805
12345