Polyhedral oxaplatinaborane chemistry:: characterisation of [9,9-(PMe2Ph)2-arachno-9,6-PtOB8H10] and its metallaborane non-oxa cognate [6,6-(PMe2Ph)2-arachno-6-PtB9H11-9-(PMe2Ph)]

被引：39
|
作者：
Kim, YH [1 ]
Brownless, A [1 ]
Cooke, PA [1 ]
Greatrex, R [1 ]
Kennedy, JD [1 ]
Pett, MT [1 ]
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 01期
基金：
英国工程与自然科学研究理事会;
关键词：
crystal structures; platinum complexes; metallaborane complexes; oxaborane cluster;
D O I：
10.1016/S1387-7003(98)00005-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [(PMe2Ph)(2)PtB8H12] with KH and [{(eta(5)-C5Me5)RhCl2}(2)] followed by chromatographic separation in air unexpectedly gave the ten-vertex oxametallaborane [9,9-(PMe2Ph)(2)-arachno-9,6-PtOB8H10] (1, 11%), which has a classical arachno ten-vertex geometry with the {O} and {Pt(PMe2Ph)(2)}, vertices in the prow (6)- and (9)-positions; the oxygen atom is therefore bound contiguously to boron atoms only. Reaction of [PtMe2(PMe2Ph)(2)] with [6,9-(PMe2Ph)(2)B10H12] generates its ten-vertex metallaborane cognate [6,6-(PMe2Ph)(2)-arachno-6-PtB9H11-9-(PMe2Ph)] (3, 10%), and completes a coherent B-->C-->N-->O cluster constituent sequence. Compounds 1 and 3 are characterised by single-crystal X-ray diffraction analysis and NMR spectroscopy. (C) 1998 Elsevier Science S.A.
引用
收藏
页码：19 / 22
页数：4
相关论文
共 50 条
12345