A new tri-parametrical law of corresponding states for subcritical dense fluids

被引:0
|
作者
Parsafar, GA [1 ]
Ghayeb, Y [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Esfahan 84154, Iran
关键词
corresponding states; supercritical; dense fluid; fluid parameter;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article introduces a new tri-parameter law of corresponding stares from the known regularities, namely the LIR and the Zeno line for dense fluids (when T<0.5T(z) = T(c)). Two of these parameters are the Zeno line Parameters and the third parameter (the fluid parameter), has been obtained from the LIR, this parameter is solely dependent upon the fluid characteristics. The third parameter can be obtained from p-v-T data of at least two different isotherms of the fluid These three parameters enable us to calculate quantities such as the density of the fluid within a reasonable accuracy (the maximum error is less than 5%). Comparing the calculated results with the experimental values shows that this law can at least be applied to spherical, polar and hydrocarbon fluids.
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页码:49 / 53
页数:5
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