α-MnO2 nanowires:: A catalyst for the O2 electrode in rechargeable lithium batteries

被引:904
|
作者
Debart, Aurelie [1 ]
Paterson, Allan J. [1 ]
Bao, Jianli [1 ]
Bruce, Peter G. [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
基金
英国工程与自然科学研究理事会;
关键词
batteries; energy conversion; lithium; manganese; nanomaterials;
D O I
10.1002/anie.200705648
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Higher-capacity lithium batteries can be fabricated by using α-MnO2 nanowires as the catalyst in a porous, composite oxygen cathode. In the depicted scanning electron micrograph of a composite positive electrode, deposits of Li2O2, which accumulates during discharge, can be seen within a porous matrix consisting of α-MnO2 and carbon. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4521 / 4524
页数:4
相关论文
共 50 条
  • [1] Pd/MnO2 Air Electrode Catalyst for Rechargeable Lithium/Air Battery
    Thapa, Arjun Kumar
    Saimen, Kazuki
    Ishihara, Tatsumi
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (11) : A165 - A167
  • [2] An O2 cathode for rechargeable lithium batteries:: The effect of a catalyst
    Debart, Aurelie
    Bao, Jianli
    Armstrong, Graham
    Bruce, Peter G.
    JOURNAL OF POWER SOURCES, 2007, 174 (02) : 1177 - 1182
  • [3] Hierarchical α-MnO2 nanowires as an efficient anode material for rechargeable lithium-ion batteries
    Umeshbabu, Ediga
    Satyanarayana, M.
    Karkera, Guruprakash
    Pullamsetty, Ashok
    Justin, P.
    MATERIALS ADVANCES, 2022, 3 (03): : 1642 - 1651
  • [4] Mesoporous α-MnO2/Pd catalyst air electrode for rechargeable lithium-air battery
    Thapa, Arjun Kumar
    Ishihara, Tatsumi
    JOURNAL OF POWER SOURCES, 2011, 196 (16) : 7016 - 7020
  • [5] Nanometer Cr2O3-doped MnO2 spheres for rechargeable lithium batteries
    X. Y. Zhan
    J. J. Tang
    Z. H. Li
    D. S. Gao
    P. Chen
    Q. Wu
    Journal of Solid State Electrochemistry, 2010, 14 : 1007 - 1011
  • [6] Nanometer Cr2O3-doped MnO2 spheres for rechargeable lithium batteries
    Zhan, X. Y.
    Tang, J. J.
    Li, Z. H.
    Gao, D. S.
    Chen, P.
    Wu, Q.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (06) : 1007 - 1011
  • [7] CHARACTERIZATION OF LITHIUM ELECTRODE SURFACE IN LI/MNO2 BATTERIES
    OKAZAKI, R
    TAKADA, K
    KONDO, S
    MIYAKE, H
    TATSUMI, E
    MATSUDA, Y
    DENKI KAGAKU, 1995, 63 (03): : 234 - 237
  • [8] Synthesis of hierarchical porous δ-MnO2 nanoboxes as an efficient catalyst for rechargeable Li-O2 batteries
    Zhang, Jian
    Luan, Yanping
    Lyu, Zhiyang
    Wang, Liangjun
    Xu, Leilei
    Yuan, Kaidi
    Pan, Feng
    Lai, Min
    Liu, Zhaolin
    Chen, Wei
    NANOSCALE, 2015, 7 (36) : 14881 - 14888
  • [9] A New Concept of an Air-Electrode Catalyst for Li2O2 Decomposition Using MnO2 Nanosheets on Rechargeable Li-O2 Batteries
    Saito, Morihiro
    Kosaka, Shinpei
    Fujinami, Taichi
    Tachikawa, Yusuke
    Shiroishi, Hidenobu
    Streich, D.
    Berg, E. J.
    Novak, Petr
    Seki, Shiro
    ELECTROCHIMICA ACTA, 2017, 252 : 192 - 199
  • [10] Rechargeable Li2O2 electrode for lithium batteries
    Ogasawara, T
    Débart, A
    Holzapfel, M
    Novak, P
    Bruce, PG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) : 1390 - 1393