Oxidation of alcohols to aldehydes and ketones using selenium ionic liquid

被引：13
|
作者：
Cheng, Xian Yi [1 ]
Li, Kang Feng [1 ]
Wang, Qiao Jian [1 ]
Wang, Cong Ying [1 ]
Ying, Tao Kai [1 ,2 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
[2] Zhejiang Normal Univ, Inst Phys Chem, Jinhua 321004, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2012年 / 23卷 / 07期
基金：
美国国家科学基金会;
关键词：
Selenium ionic liquids; Aldehydes; Ketones; Oxidation;
D O I：
10.1016/j.cclet.2012.05.019
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new type of ionic liquid supported selenium reagents were synthesized and found to be an excellent catalyst in the oxidation of alcohols to aldehydes and ketones in the presence of 30% H2O2. The predictable solubility of ionic liquids allows an easy separation of the oxidation products from the reaction mixture. Furthermore, the oxidation reaction can be carried out using an ionic liquid as the solvent, and the ionic liquid-supported selenium reagents can be recycled and used for four times with a little decrease in catalytic performance. (C) 2012 Tao Kai Ying. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：801 / 804
页数：4
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