Pyrolysis of de-oiled seed cake of Jatropha Curcas and catalytic steam reforming of pyrolytic bio-oil to hydrogen

被引:16
|
作者
Renny, Andrew [1 ]
Santhosh, Viswanathan [2 ]
Somkuwar, Nitin [1 ]
Gokak, D. T. [1 ]
Sharma, Pankaj [2 ]
Bhargava, Sanjay [1 ]
机构
[1] Bharat Petr Corp Ltd, Corp R&D Ctr, Greater Noida, Uttar Pradesh, India
[2] Univ Petr & Energy Studies, Coll Engn, Dehra Dun, Uttarakhand, India
关键词
Steam reforming; Hydrogen yield; Steam activation; BIOMASS FAST PYROLYSIS; AQUEOUS-PHASE; GASIFICATION; PRODUCTS; QUALITY; CARBON; LIQUID; WASTE; YIELD;
D O I
10.1016/j.biortech.2016.08.052
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The aim of this work was to study the pyrolysis of de-oiled seed cake of Jatropha Curcas and catalytic steam reforming of pyrolytic bio-oil to hydrogen. As per literature, presence of heavy nitrogenous and oxygenated compounds leads to catalyst deactivation. Here, an attempt has been made to tune pyrolytic reactions to optimize the N and O content of the pyrolytic bio-oil. Bio-oil conversion and hydrogen yield decreased as reaction progressed, which attributes to temporary loss of catalytic activity by blockage of catalyst pores by carbon deposition. Further, retention of steam reforming activity after repetitive steam activation suggests long-term catalyst usage. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:151 / 160
页数:10
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