Platinum(II)-Catalyzed Generation and [3+2] Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates for the Preparation of Polycyclic Compounds

被引：89

作者：

Saito, Kodai ^{[1
]}

Sogou, Hideyuki ^{[1
]}

Suga, Takuya ^{[1
]}

Kusama, Hiroyuki ^{[1
]}

Iwasawa, Nobuharu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 04期

关键词：

CATALYZED CYCLOISOMERIZATION; PLATINUM CATALYSIS; PROPARGYLIC ESTERS; GOLD CATALYSIS; ENYNYL ESTERS; CYCLOPROPANATION; CARBOCYCLES; DIVERSITY; INDOLE;

D O I：

10.1021/ja108586d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pt(II)-catalyzed generation of unsaturated carbene complex intermediates from various propargyl ether derivatives based on electrophilic activation of alkynes was realized. These in situ generated unsaturated carbene complexes undergo [3+2] cycloaddition reaction with various vinyl ethers, leading to efficient formation of indoles, naphthols, and benzofuran fused with a five-membered ring in high yields.

引用

页码：689 / 691

页数：3

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