Diaminomaleonitrile-functionalized gelators in F-/CN-sensing, phase-selective gelation, oil spill recovery and dye removal from water

被引:17
|
作者
Raza, Rameez [1 ]
Panja, Atanu [1 ]
Ghosh, Kumaresh [1 ]
机构
[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India
关键词
EFFICIENT CATALYTIC-REDUCTION; SUPRAMOLECULAR GELATORS; COMPOSITE HYDROGELS; FLUORIDE-ION; CHOLESTEROL CONJUGATE; METAL-IONS; TOXIC DYES; GEL; SOL; HG2+;
D O I
10.1039/d0nj01992e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Diaminomaleonitrile-based gelators1and2, which describe the linking of diaminomaleonitrile as an H-bonding site to the cholesterol unitviaan aromatic linker (naphthalene/benzene), have been synthesized. They form gels from various organic and aqueous organic solvents. Aggregation of the gelators occurs due to several weak forces (e.g., hydrophobic interactions, H-bonding and pi-stacking interactions) in solutions. Compound1is a superior gelator as compared to2and is capable of forming gels from 15 out of the 20 solvents tested. The gelators show multiple applications. Toluene and 1,2-dichlorobenzene gels of1and2, respectively, can sense F(-)and CN(-)anions by showing gel-to-sol transformation. These ions are distinguished with the aid of Fe3+. In the designs, changes in the linker group (naphthalene/benzene) influence the gelation behaviors and gel properties (mgc, thermal stability, morphology and mechanical behavior) of the gelators. The naphthyl analogue1exhibits self-healing behavior in contrast to the benzene analogue2. Both1and2show phase-selective gelation (PSG) from biphasic mixtures of water and hydrocarbons/oils. The toluene gel of1serves as an excellent injectable material and has been applied in environmental remediation (e.g., oil spill recovery and removal of water-soluble toxic dyes).
引用
收藏
页码:10275 / 10285
页数:11
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