Preparation of trifluoromehtyl-substituted alcohols from allylsilanes and trifluoroacetic anhydride.

被引：19
|
作者：
Pellissier, H [1 ]
Wilmouth, S [1 ]
Santelli, M [1 ]
机构：
[1] FAC SCI & TECH ST JEROME,ORGAN SYNTH LAB,CNRS 1411,F-13397 MARSEILLE,FRANCE
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 29期
关键词：
D O I：
10.1016/0040-4039(96)01045-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The titanium tetrachloride-mediated addition of allyltrimethylsilane or 1,8-bis(trimethylsilyl)-2,6-octadiene and trifluoroacetic anhydride led to trifluoromethyldiallylcarbinol or (dl)-1-trifluoromethyl-2,5-divinylcyclopentanol, respectively, in fair yields; this latter was further converted into several 1-trifluoromethyl-2-vinylcyclopentane derivatives. Copyright (C) 1996 Published by Elsevier Science Ltd
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页码：5107 / 5110
页数：4
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