Hydrogenation of carbon dioxide over rhodium catalyst supported on silica

被引:0
|
作者
Kishida, M [1 ]
Onoue, K [1 ]
Tashiro, S [1 ]
Nagata, H [1 ]
Wakabayashi, K [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Mat Proc Engn, Chem Engn Grp,Higashi Ku, Fukuoka 81281, Japan
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this work, it was found that the surface area of silica-supported rhodium catalysts could be controlled in the range between 60 and 600m(2)/g by using the preparation method which we have developed using water-in-oil microemulsion. The catalysts with a controlled surface area had the same average size of rhodium particles. By using these catalysts, it was also found that turnover frequencies for CO2 hydrogenation increased linearly with the catalyst surface area.
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页码:411 / 414
页数:4
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