A concise total synthesis of (±)-cipadonoid B from synthetic azedaralide

被引:19
|
作者
Faber, Jonathan M. [1 ]
Williams, Craig M. [1 ]
机构
[1] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld 4072, Australia
关键词
KETAL CLAISEN REARRANGEMENT; ALLYL VINYL ETHERS; JUVENILE-HORMONE; LIMONOIDS; CYCLIZATION; CHEMISTRY; MELIACEAE; PRODUCTS; EXCHANGE;
D O I
10.1039/c0cc04698a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The tetranortriterpene cipadonoid B was efficiently constructed from synthetic azedaralide in a one-pot cascade, via the underutilised ketal-Claisen rearrangement.
引用
收藏
页码:2258 / 2260
页数:3
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