Near infrared photoluminescence modulation by defect site design using aryl isomers in locally functionalized single-walled carbon nanotubes

被引:38
|
作者
Shiraki, Tomohiro [1 ,2 ]
Uchimura, Shunsuke [1 ]
Shiraishi, Tomonari [1 ]
Onitsuka, Hisashi [1 ]
Nakashima, Naotoshi [2 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Fukuoka, Japan
关键词
ELECTRONIC-STRUCTURE; STATES; RECOGNITION; STRAIN; IMPACT;
D O I
10.1039/c7cc06663e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We newly introduce positional isomeric structures at the defect sites of locally-functionalized single-walled carbon nanotubes (lf-SWNTs) showing unique near infrared photoluminescence (PL). The observed PL is significantly different from that of typical paraaryl modified lf-SWNTs; i.e., (i) an extraordinary PL wavelength shift of the meta-aryl modified lf-SWNTs, and (ii) remarkably red-shifted PL from the ortho-aryl modified lf-SWNTs are revealed.
引用
收藏
页码:12544 / 12547
页数:4
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