Autothermal Reforming of Methane under low Steam/Carbon ratio on supported Pt Catalysts

被引：0
|
作者：
Ruiz, Juan A. C. [1 ]
Passos, Fabio B.
Bueno, Jose M. C.
Souza-Aguiar, E. F.
Mattos, Lisiane V. [1 ]
Noronha, Fabio B. [1 ]
机构：
[1] Inst Nacl Tecnol, BR-20081312 Rio De Janeiro, Brazil
来源：
NATURAL GAS CONVERSION VIII, PROCEEDINGS OF THE 8TH NATURAL GAS CONVERSION SYMPOSIUM | 2007年 / 167卷
关键词：
D O I：
暂无
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Pt/Ce(0.75)Zr(0.25)O(2), Pt/Ce(0.14)Zr(0.86)O(2) and Pt/CeO(2) catalysts proved to be more stable than Pt/Ce(0.50)Zr(0.50)O(2), Pt/CeO(2) (prec), Pt/ZrO(2) and Pt/Al(2)O(3) catalysts on the autothermal reforming of methane under low S/C ratio (0.2). The results showed that the good stability of the Pt/Ce(0.75)Zr(0.25)O(2), Pt/Ce(0.14)Zr(0.86)O(2) and Pt/CeO(2) catalysts is related to a proper amount of oxygen available per metal-support interfacial area on these materials. The high reducibility and oxygen storage/release capacity of support promotes the mechanism of continuous removal of carbonaceous deposits from the active sites, which takes place at the metal-support interfacial perimeter.
引用
收藏
页码：249 / 254
页数：6
相关论文
共 50 条
  • [1] Study of the mechanism of the autothermal reforming of methane on supported Pt catalysts
    Souza, MMVM
    Sabino, S
    Passos, FB
    Mattos, LV
    Noronha, FB
    Schmal, M
    NATURAL GAS CONVERSION VII, 2004, 147 : 253 - 258
  • [2] Study of the properties of supported Pd catalysts for steam and autothermal reforming of methane
    Cassinelli, W. H.
    Damyanova, S.
    Parizotto, N. V.
    Zanchet, D.
    Bueno, J. M. C.
    Marques, C. M. P.
    APPLIED CATALYSIS A-GENERAL, 2014, 475 : 256 - 269
  • [3] Development of Supported Ni Catalysts for Autothermal Reforming of Methane
    Matus, E., V
    Vasil'ev, S. D.
    Ismagilov, I. Z.
    Ushakov, V. A.
    Kerzhentsev, M. A.
    Ismagilov, Z. R.
    CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2020, 28 (04): : 403 - 411
  • [4] Syngas production by autothermal reforming of methane on supported platinum catalysts
    Ruiz, Juan A. C.
    Passos, Fabio B.
    Bueno, Jose M. C.
    Souza-Aguiar, Eduardo F.
    Mattos, Lisiane V.
    Noronha, Fabio B.
    APPLIED CATALYSIS A-GENERAL, 2008, 334 (1-2) : 259 - 267
  • [5] Carbon formation and steam reforming of methane on silica supported nickel catalysts
    Guo, Xueyan
    Sun, Yanli
    Yu, Yue
    Zhu, Xinli
    Liu, Chang-Jun
    CATALYSIS COMMUNICATIONS, 2012, 19 : 61 - 65
  • [6] Pt Supported Catalysts for Steam Reforming Reaction
    Ghita, Danuta
    Ezeanu, Dorin Stanica
    Cursaru, Diana
    Rosca, Paul
    REVISTA DE CHIMIE, 2012, 63 (12): : 1296 - 1300
  • [7] Catalytic autothermal reforming of methane and propane over supported metal catalysts
    Ayabe, S
    Omoto, H
    Utaka, T
    Kikuchi, R
    Sasaki, K
    Teraoka, Y
    Eguchi, K
    APPLIED CATALYSIS A-GENERAL, 2003, 241 (1-2) : 261 - 269
  • [8] Rapid evaluation of coke resistance in catalysts for methane reforming using low steam-to-carbon ratio
    Jeon, Jiyoon
    Nam, Seongju
    Ko, Chang Hyun
    CATALYSIS TODAY, 2018, 309 : 140 - 146
  • [9] Optimization of the Reaction Conditions of Steam/Carbon Dioxide and Autothermal Reforming of Methane
    Mikhaylova, E. S.
    V. Salnikov, A.
    Khairulin, S. R.
    CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2023, 31 (01): : 59 - 63
  • [10] Comparison of Rh, Pt and Rh-Pt supported on an oxide-ion conducting substrate as catalysts for autothermal reforming methane
    Cronauer, Donald C.
    Krause, Theodore
    Salinas, Jon
    Wagner, Aaron L.
    Wagner, Jon P.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
12345