Multiple bonding in heavier element compounds stabilized by bulky terphenyl Ligands

被引：218
|
作者：
Rivard, Eric [1 ]
Power, Philip P. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 24期
关键词：
D O I：
10.1021/ic700813h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper summarizes recent developments involving the preparation and reactivity of molecular species stabilized by terphenyl ligands that feature new bonding environments. Highlights include the synthesis and characterization of dimetallenes and dimetallynes, ArEEAr [E = heavy group 13 (triel) or group 14 (tetrel) element, Ar = terphenyl ligand] and, more recently, the synthesis of a stable chromium(I) dimer, ArCrCrAr, that displays a 5-fold bonding interaction between the chromium centers.
引用
收藏
页码：10047 / 10064
页数：18
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