Intervalence Charge-Transfer System by 1D Assembly of New Mixed-Valence Octanuclear CuI/CuII/CuIII Cluster Units

被引：16
|
作者：
Okubo, Takashi [1 ,2 ]
Kuwamoto, Hiroyasu [1 ]
Kim, Kyung Ho [1 ]
Hayami, Shinya [3 ]
Yamano, Akihito [4 ]
Shiro, Motoo [4 ]
Maekawa, Masahiko [1 ]
Kuroda-Sowa, Takayoshi [1 ]
机构：
[1] Kinki Univ, Sch Sci & Engn, Higashiosaka, Osaka 5778502, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
[3] Kumamoto Univ, Fac Sci, Dept Chem, Kumamoto 8608555, Japan
[4] Rigaku Corp, Akishima, Tokyo 1968666, Japan
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 07期
关键词：
COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MMX-CHAIN; COMPLEXES; RUTHENIUM; BEHAVIOR; SERIES;
D O I：
10.1021/ic101794u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Cu(Hm-dtc)(2), Br-2, and CuBr2 yielded a new mixed-valence octanuclear Cu-I/Cu-II/Cu-III cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from Cu-II ions to Cu-III ions between the clusters.
引用
收藏
页码：2708 / 2710
页数：3
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