Synthesis and thermal expansion property of cubic CS2MSi5O12 (M = Cd, Ni, Zn) powders

被引：7
|
作者：
Yanase, I
Miyashita, N
Kobayashi, H
Noguchi, F
Mitamura, T
机构：
[1] Saitama Univ, Fac Engn, Dept Appl Chem, Urawa, Saitama 3388570, Japan
[2] Saitama Inst Technol, Fac Engn, Okabe, Saitama 3690293, Japan
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 1998年 / 106卷 / 11期
关键词：
leucite; CS2CdSi5O12; CS2NiSi5O12; Cs2ZnSi5O12; thermal expansion;
D O I：
10.2109/jcersj.106.1099
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Monolithic Cs2MSi5O12(M=Cd, Ni, Zn) with cubic symmetry, space group Ia (3) over bar d, was synthesized in air according to a two stage heat treatment. Mixed raw material powders were calcined at 973 to 1023 K for 20 to 40h until the Cs2MSi5O12(M=Cd, Ni, Zn) phase were recognized by XRD and then they were heated at 1273 to 1473 K for 20h. The thermal expansion of the synthesized Cs2MSi5O12(M=Cd, Ni, Zn) powders was investigated using high-temperature X-ray diffraction at 298 to 1273 K. The Cs2MSi5O12(M=Cd, Ni, Zn) powders having SiO4/MO42-=5, displayed a lower thermal expansion than those of CsMSi2O5(M=Al, Fe) having SiO4/MO4- = 2 in the low temperature range. With increasing the ionic radius of M2+, the thermal expansion coefficient of the synthesized Cs2MSi5O12(M=Cd, Ni, Zn) was increased in the low temperature range.
引用
收藏
页码：1099 / 1103
页数：5
相关论文
共 50 条
  • [1] Synthesis and thermal expansion property of cubic Cs2MSi5O12 (M = Cd, Ni, Zn) powders
    Yanase, Ikuo
    Miyashita, Norihiko
    Kobayashi, Hidehiko
    Noguchi, Fumio
    Mitamura, Takashi
    Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, 1998, 106 (1239): : 1099 - 1103
  • [2] Synthesis of cubic Cs2FeSi5O12 powder in Ar atmosphere and its thermal expansion property
    Yanase, I
    Kobayashi, H
    Mitamura, T
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2000, 108 (07) : 677 - 680
  • [3] Synthesis of cubic Cs2FeSi5O12 powder in Ar atmosphere and its thermal expansion property
    Yanase, Ikuo
    Kobayashi, Hidehiko
    Mitamura, Takashi
    Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, 2000, 108 (1259): : 677 - 680
  • [4] Synthesis of Negative Thermal Expansion Materials of Cubic ZrMo2O8 Ultrafine Powders
    Liu Qinqin
    Yang Juan
    Sun Xiujuan
    Cheng Xiaonong
    RARE METAL MATERIALS AND ENGINEERING, 2008, 37 : 374 - 377
  • [5] Synthesis and thermal expansion property of Y2-xLaxMo3O12 ceramics
    Meng, Xiangdong
    Wang, Xiaocen
    Zhang, Zhiping
    Zeng, Xianghua
    Liu, Hongfei
    Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society, 2012, 40 (12): : 1734 - 1738
  • [6] SYNTHESIS AND STRUCTURE OF A NEW FAMILY OF PHASES, A2MGE5O12 - A = RB, CS - M = BE, MG, CO, ZN
    TORRESMARTINEZ, LM
    GARD, JA
    WEST, AR
    JOURNAL OF SOLID STATE CHEMISTRY, 1984, 53 (03) : 354 - 359
  • [7] Phase Relations in MO-M'O-V2O5 (M, M' = Cd, Zn, Ni, Mn) Systems
    Surat, L. L.
    Zhuravlev, V. D.
    Fotiev, A. A.
    Velikodnyi, Y. A.
    Russian Journal of Inorganic Chemistry, 1996, 41 (08)
  • [8] Phase relations in MO-M'O-V2O5 systems (M, M'=Cd, Zn, Ni, Mn)
    Surat, LL
    Zhuravlev, VD
    Fotiev, AA
    Velikodnyi, YA
    ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (08): : 1370 - 1372
  • [9] Synthesis and negative thermal expansion property of Y2-xLaxW3O12 (0 ≤ x ≤ 2)
    Liu, Hongfei
    Zhang, Zhiping
    Zhang, Wei
    Zeng, Xianghua
    Chen, Xiaobing
    CERAMICS INTERNATIONAL, 2013, 39 (03) : 2781 - 2786
  • [10] Synthesis and tunable thermal expansion property of Al2-δScδW3O12
    Zhu, Junjun
    Yang, Juan
    Cheng, Xiaonong
    SOLID STATE SCIENCES, 2012, 14 (01) : 187 - 190
12345