Synthesis of new iminocoumarins and their transformations into N-chloro and hydrazono compounds

被引:73
|
作者
Volmajer, J
Toplak, R
Leban, I
Le Marechal, AM
机构
[1] Univ Maribor, Fac Mech Engn, SLO-2000 Maribor, Slovenia
[2] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia
关键词
Knoevenagel condensation; iminocoumarins; coumarins; N-chlorination; N-chloro iminocoumarins; N-hydrazonocumarins;
D O I
10.1016/j.tet.2005.05.020
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Knoevenagel reaction between 2-hydroxybenzaldehydes and active methylene compounds (malononitrile and ethyl cyanoacetate) produces iminocoumarins and/or coumarins. In order to study the reactivity of the prepared iminocoumarins, chlorination and reaction with N-nucleophiles were studied. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7012 / 7021
页数:10
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