Unusual metal-organic network constructed from Zn(II), benzenetricarboxylate and bis(1,2,4-triazolyl)pyridine

被引：29
|
作者：
Liang, Sheng-Wen
Li, Ming-Xing [1 ]
Shao, Min
Liu, Hong-Jiang
机构：
[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Instrumental Analysis & Res Ctr, Shanghai 200444, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 11期
关键词：
1,3,5-Benzenetricarboxylic acid; 2,6-Bis(1,2,4-triazolyl)pyridine; metal-organic framework; crystal structure;
D O I：
10.1016/j.inoche.2007.08.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reaction of ZnSO4 center dot 7H(2)O with 1,3,5-benzenetricarboxylic acid (H(3)btc) and 2,6-bis(1,2,4-triazolyl)pyridine (btp) afforded a novel metal-organic network {[Zn-3(btc)(2)(btp)(2)(H2O)(2)]center dot 4H(2)O}(n) (1) with a supramolecular cocrystal [H(3)btc center dot btp center dot H2O](n) (2). The complex I exhibits an unusual network containing two molecular squares and a rectangle. The networks interpenetrate to make a 3D metal-organic framework, which is quite thermal stable. Compound 2 shows a 2D supramolecular network assembled through strong hydrogen bonds. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：1347 / 1350
页数：4
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