PTh;
Bi4O5I2;
Photocatalytic;
BPA;
Nanocomposites;
INTERFACIAL CHARGE-TRANSFER;
FACILE SYNTHESIS;
REACTION-MECHANISM;
NO REMOVAL;
HETEROJUNCTION;
MICROSPHERES;
COMPOSITES;
HETEROSTRUCTURE;
CONTAMINANTS;
PERFORMANCE;
D O I:
10.1016/j.jallcom.2020.153773
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
In this contribution, polythiophene (PTh)/Bi4O5I2 nanocomposites are successfully synthesized through a facile route at room temperature, and evaluated as photocatalysts for the photocatalytic degradation of bisphenol a (BPA). It was discovered that the introduction of polythiophene (PTh) obviously enhanced the separation efficiency of photocharge carriers, thus promote the photocatalytic ability of Bi4O5I2. Among the as-prepared PTh/Bi4O5I2 nanocomposites, 0.5% PTh/Bi4O5I2 exhibited the optimal photocatalytic activity, the BPA degradation rate was 99.2% in 30 min. The reaction rate is about 3.7 times as high as that of pure Bi4O5I2. Moreover, the degradation products of BPA were analyzed by high performance liquid chromatography. The good stability of the composite was discovered by cyclic experiments. Finally, a possible photocatalytic mechanism was proposed. (C) 2020 Elsevier B.V. All rights reserved.
机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
Gao, Peng
Li, Zexin
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机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
Li, Zexin
Feng, Li
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机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
Feng, Li
Liu, Yongze
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机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
Liu, Yongze
Du, Ziwen
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机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
Du, Ziwen
Zhang, Liqiu
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机构:
Beijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R ChinaBeijing Forestry Univ, Engn Res Ctr Water Pollut Source Control & Ecorem, Beijing Key Lab Source Control Technol Water Poll, Beijing 100083, Peoples R China
机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
Gao, Peng
Li, Zexin
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h-index: 0
机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
Li, Zexin
Feng, Li
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机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
Feng, Li
Liu, Yongze
论文数: 0引用数: 0
h-index: 0
机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
Liu, Yongze
Du, Ziwen
论文数: 0引用数: 0
h-index: 0
机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
Du, Ziwen
Zhang, Liqiu
论文数: 0引用数: 0
h-index: 0
机构:
Beijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, ChinaBeijing Key Laboratory for Source Control Technology of Water Pollution, Engineering Research Center for Water Pollution Source Control and Eco-remediation, Beijing Forestry University, Beijing,100083, China
机构:
Sun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R ChinaSun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
Xiao, Xujing
Lin, Ying
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h-index: 0
机构:
Sun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R ChinaSun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
Lin, Ying
Pan, Bole
论文数: 0引用数: 0
h-index: 0
机构:
Guangzhou Tianhe Foreign Language Sch, Guangzhou, Guangdong, Peoples R ChinaSun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
Pan, Bole
Fan, Wenjie
论文数: 0引用数: 0
h-index: 0
机构:
South China Normal Univ, Anal & Testing Ctr, Guangzhou 510006, Guangdong, Peoples R ChinaSun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
Fan, Wenjie
Huang, Yongchao
论文数: 0引用数: 0
h-index: 0
机构:
Sun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
Guangzhou Univ, Res Inst Environm Res Greater Bay, Key Lab Water Qual & Conservat Pearl River Delta, Minist Educ, Guangzhou 510006, Guangdong, Peoples R ChinaSun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
机构:
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China
Chang, Fei
Wang, Xiaomeng
论文数: 0引用数: 0
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机构:
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China
Wang, Xiaomeng
Li, Sushi
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机构:
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China
Li, Sushi
Chen, Hongyu
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机构:
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China
Chen, Hongyu
Wang, Yuqing
论文数: 0引用数: 0
h-index: 0
机构:
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China
Wang, Yuqing
Liu, Deng-guo
论文数: 0引用数: 0
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机构:
Shanghai Environmental Monitoring Center, Shanghai,200235, ChinaSchool of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai,200093, China